Thursday, October 5, 2023

Lavoisier, father of modern chemistry

Lavoisier

Antoine Laurent de Lavoisier is considered the father of modern Chemistry, having introduced the quantitative method into this science. In 1768, aged 25, he was elected a member of the Academy of Sciences. The astronomer Joseph Jérôme Lalande, who defended his candidacy, explained it this way:

A young man with knowledge, ingenuity, activity, whom fortune exempts from practicing another profession, would naturally be of great use to the sciences.

Indeed, his mother’s family inheritance allowed him to buy a position in a financial company called Ferme générale, whose members were responsible of collecting taxes on behalf of the king, a position he held until 1791 and which eventually led him to the grave. Here he met his future wife, Marie-Anne Paulze, whom he married in 1771 when she was 13, who became his best scientific collaborator.

His greatest success was the theory of oxidation. Until then it was thought (according to the phlogiston theory, by Georg Ernst Stahl) that when a body burns or oxidizes, it loses part of its substance. Lavoisier showed that what happens is precisely the opposite: when a body burns it combines with a gas, oxygen, a name invented by Lavoisier. He is also the author of the law of conservation of matter:

Matter is neither created nor destroyed. And water cannot become earth.

Lavoisier asserted that the bodies called metallic earths are not simple, but oxides. After repeating the experiment of Henry Cavendish, discoverer of hydrogen, he said that water is not a simple body, but a compound of oxygen and hydrogen, a name also invented by Lavoisier.

He redefined the concept of chemical element. Since ancient times everyone spoke about four elements: earth, water, air, and fire. After the experiments of Lavoisier and his predecessors, it was shown that water and air are not elements. Lavoisier defined a chemical element as a substance that cannot be decomposed, and proposed a list that included oxygen, hydrogen, nitrogen, sulfur, phosphorus, mercury, and zinc, although he also included light and heat, which we now know are not chemical elements, but forms of energy.

At the beginning of the French Revolution, Lavoisier was appointed national commissioner of the committee for the uniformity of weights and measures, which promoted the establishment of the metric system. In 1791 the tax collection department was abolished and Lavoisier lost his living. On November 24, 1793, the Revolutionary Convention decreed the imprisonment of those who had held the position of tax collector. There were requests advocating the release of Lavoisier. The Weights and Measures Commission sent a letter in his favor. The Commission said that the work... was interrupted by the arrest of this citizen and it was urgent for him to return to carrying out important work that he has always carried out with zeal and activity. The response was the expurgation of the Commission: Borda, Lavoisier, Laplace, Coulomb, Brisson and Delambre were immediately dismissed.

When the tax collectors were sent to trial, some of the defendants planned to commit suicide with an excessive dose of opium, and offered it to Lavoisier, who dissuaded them thus:

Why should we anticipate death? Is it shameful to receive it by an unjust order? The excess of injustice erases shame... To commit suicide would be to absolve those who send us to death. Let us think of those who have preceded us and let us also set a good example for those who follow us.

These words by Lavoisier convinced his companions, none of whom committed suicide. Thanks to this, one of them saved his life, because he was not sentenced with the others.

It is said that when Hallé, defender of the accused, presented a report recalling the scientific works of Lavoisier, Jean-Baptiste Coffinhal, vice president of the Revolutionary Tribunal, answered this:

The Republic does not need wise men; justice must follow its course.

The collectors were sentenced to death on May 8, 1794, and that same day they all died by guillotine.

Lagrange

The next day, when the news broke, Joseph Louis de Lagrange, director of the commission that established the metric system, exclaimed:

A moment has sufficed to cut off his head, and perhaps a century will not suffice to produce another like it.

Less than a year after the execution, Lavoisier’s widow petitioned the Convention for the return of her husband’s property that had been confiscated, leaving her destitute, and when it was granted, the restitution order had the following phrase:

Widow of Lavoisier, unjustly condemned.

Lavoisier was a devout Catholic all his life. A note written by his widow says this:

It was [in his laboratory] where one had to see and hear this man with such a just spirit, such a pure talent, such a high genius; it was in his conversation that one could judge the height of his moral principles.

The same post in Spanish


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Manuel Alfonseca

Excerpt from my article in the book La cosmovisión de los grandes científicos de la Ilustración

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